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New carbon dioxide scrubber

JAN 10, 2012
Physics Today
Science : A new kind of plastic that can remove large amounts of CO 2 from the air has been produced by a research team led by George Olah of the University of Southern California in Los Angeles. Olah and his team needed a CO 2 absorber for iron-based batteries they were working on; they tried using polyethylenimine (PEI), an inexpensive CO 2 absorbing polymer. PEI grabs CO 2 only on its surface, so to increase its surface area, Olah dissolved the polymer in a methanol solvent and spread it atop a batch of fumed silica, an industrially produced porous solid made from microscopic droplets of glass fused together. When the solvent evaporated, it left solid PEI with a high surface area. When the team tested the new material’s ability to absorb CO 2, they found that in humid air each gram of the material absorbed an average of 1.72 nanomoles of CO 2. That’s one of the highest levels of CO 2 absorption from air ever tested. The material also sheds CO 2 when it’s heated to 85 °C, whereas other solid CO 2 absorbers have to be heated to over 800 °C to shed CO 2. The new polymer could be used to scrub CO 2 from the air, although it couldn’t be used in industrial smokestacks or automobile tailpipes without additional tinkering to make it more heat-resistant.
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